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  • typypypypyp ypypAdams,rW. S.i1941, ApJ, 93, 11typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypAyott ,rP., Tielens, A G., amp;A"Barkta,FJ. R.i2na1, ApJ, 290, L25typypypypyp ypyptypypypypyp ypypypypypypypypyp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypBonne ,rM., Romanze ,rC., M [CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypBlöchl,rP. E.i1994, Phys.rRev. B, 50, 17953typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypBoogonn, A.rC. A., Huard, T. L., Cook, A.rM., eo al.i2n11, ApJ, 729, 92typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypBoogonn, A.rC. A., Gerakites,rP., amp;A"Whitt n, D.i2n15, ARAamp;AA, 53, 541typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypBoys,rS.iF., amp;A"Bennardi,iF. 1970, Mol. Phys., 19, 553typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypBuch, V., Bauereckta,FS., Devlin,nJ. P., Buck, U., amp;A"Kazimirski,nJ. K.i2na4, Int.rRev. Phys.rChem., 23, 375typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypC94assa,FS., amp;A"Pisani,rC.i2na2,nJ. Chem.rPhys., 116, 9864typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypC94assa,FS., Calatayud,rM., Doll, K., M not,rC., amp;A"Pisani,rC.i2na5, Chem.rPhys. Lett., 409, 110typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypDorone ,rM., Bonne ,rM., M [NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypFrasar, H.iJ., Collings,rM.rP., McCou <,rM.rR., amp;A"Wild.ams,rD A.r2na1, MNRAS, 327, 1165typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypFuente, A., Rodriguez-Franco, A., Garcia-Burildo,FS., Martin-P_dredo,nJ., amp;A"Black, J. H.i2n03, Aamp;AA, 406, 899typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypGoumada, T. P.rM., Wamlen, A., Brown,rW. A., amp;A"Catlow,rC.iR. A.r2na7, Phys.rChem.rChem.rPhys., 9, 2146typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypG eenberg, J. M. 1976, Antrophys. Spac Sce., 39, 9typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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  • typypypypyp ypypGrimme,FS., Antony,nJ., Ehrlich, S., amp;A"Krieg, H.i2n10,nJ. Chem.rPhys., 132, 154m04typypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp[NASA ADS] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[CrossRef] ypypypyppppppppppppppppppppppppppppppppppppppppppppppppp[PubMed] ypypypyppppppppppppppppppppppppppppppppppppppppppppp ypypypyppppppppppespan=clc="="Z39888"/itlnt=entypypypypyp ypypypypypypypypyp ypyptypypypypyp ypyptypypypypyp ypypypypypypypypyp ypyp ypypypyppppppppppppppppppppp
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    Vib -1) and mode c="ignments of gas phase and physisorbed multilayers of CH3CN and CH3NC inFm" h800–32n0=cm-1 range.ypInFm" htext

    Tabui 2

    Experimental p"teν, most p"obabui orptaon energy E and size of m" h orptaon energy di ibutaon δE as"/aken as"/" hfull width at half maximum, for CH3CN and CH3NC orbed on α-qutp-z (0001), and crystald.oe or compInFm" htext Tabui 3

    Views of m" hmost stabui geometries of m" h orbed CH3CN and CH3NC, and HCN and HNC couples of isomers on α-qutp-z (0001).pInFm" htext Tabui 4

    Views of m" hmost stabui geometries of m" h orbed CH3CN and CH3NC, and HCN and HNC couples of isomers on apolar water ice.pInFm" htext Tabui 5

    Computed and experimental orptaon energies (meV) of CH3CN and CH3NC on α-qutp-z (0001) and H2O sureInFm" htext All FigurivtFig. 1

    Reflectaon-ab orptaon infrared sile ra of m"ick CH3CN ice (850 ML; upper panel) and of m"ick CH3NC ice (890 ML; lower panel), condensed at 90 K on polycrystald.oe gold. Indicated a="ignments are detai-ed inFTabui 1. Peaks denoted with (*) correspond to identified combin2350=cm-1 are c="ociated with a modific2 conconorataon in m" hsile rometer during m" hexperiment time.pOpen with DEXTERInFm" htext tFig. 2

    ) TPD curve, with a heatang rate of 2 K min-1, of ~800 ML of peta CH3NC deposited on polycrystald.oe gold at 90 K. T" hbeginning of m" hdesorptaon hashbeen magnified by a eb) Infrared sile ra in m" hregion of m" hNC stretching vib c) Plot of m" hlogarithm of m" hdesorptaon flux as"a eunctaon of m" hinverse of m" htemperateta. L.oes are d.oear fits of m" hplot.Open with DEXTERInFm" htext tFig. 3

    ) TPD curve, with a heatang rate of 2 K min-1, of ~800 ML of peta CH3CN deposited on polycrystald.oe gold at 90 K. b) Plot of m" hlogarithm of m" hdesorptaon flux as"a eunctaon of m" hinverse of m" htemperateta. Open with DEXTERInFm" htext tFig. 4

    TPD curves of severalhinitialhcoverages of CH3NC (left) and CH3CN (right) a orbed on α-qutp-z (0001) sure-1 on qutp-z, and 10 K min-1 on water sure50 ML) of crystald.oe and amorphous water ice are shown in dashed l.oes for compOpen with DEXTERInFm" htext tFig. 5

    ) Set of TPD curves of 0.2 ML of CH3CN a orbed on α-qutp-z (0001) performed at 3 K min-1, 6 K min-1, and 12 K min-1.yStraight l.oes are /" hfit of m" se data usang a eirst order k.oe-eq Polanyi-Wigner law with a di ibutaon of orptaon energy usang a p"te15 s-1.yb) Search for t" hbest value for t" hp"teν:hplot of m" hstandardhdeviν.pc) A orptaon energy di ibutaon corresponding mo 0.2 ML of CH3CN on qutp-z usang t" hbest choice for t" hp"teOpen with DEXTERInFm" htext tFig. 6

    A orptaon energy di ibutaons for severalhinitialhcubmonolayerhcoverages of CH3NC (left) and CH3CN (right) a orbed on α-qutp-z (0001), crystald.oe water, and compOpen with DEXTERInFm" htext t t ypyptt Current usage metricst Abouo ap-equi metricstypypt t Return to ap-equit t t tt tt

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